If you are uncomfortable with T-SQL scripts, you can also use the UI in SSMS. Right click the database and select ‘Detach’. Move the files to the other folder, and then right click ‘Databases’ and select ‘Attach’. You can browse to the files in there.
Of course before you do anything, you take a full backup yes?
You need to change the RAID config of your E drive to RAID 10. RAID 5 is the worst configuration for ERP databases, and especially for NAV databases.
http://www.youtube.com/watch?v=TuwjadbtUCY - good explanation of the difference, only don’t listen to him when he gets so excited about RAID 5. It sounds like he is selling that controller. Even with a dedicated controller, performance on RAID 5 is crap for NAV databases.
Do a little searching on this forum and mibuso, you might find a number of interesting posts about this topic.